Tungsten oxide electrochromic film is a dingal material, and the smart window prepared using it as the electrochromic layer material exhibits a reversible change in color and transparency in appearance performance. As the color of the glass deepens, the heat-insulating effect of the obtained electrochromic window is improved, and the energy-saving effect is more remarkable, so that it is more and more widely applied in the energy saving reconstruction of building.
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According to experts, the tungsten oxide film can be prepared by electrodeposition method. Experts say that when WO3 film is prepared by electrodeposition, it is generally carried out in a tungstic acid solution. The electrodeposition reaction equation is shown as below:
W2O2-11+(2+x)H++xe-→2WO3+2+x2H2O+8?X4O2
In the formula, W2O2-11 is a peroxytungstate ion. The WO3 film prepared by electrodeposition is amorphous, containing a large amount of water. And since it is deposited by a cathode, H+ ions are embedded in the film, so that the generated film is blue.
